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Elements of Chemistry: The Author’s Preface

化学基础论:作者序

原题:Traité élémentaire de chimie: Discours préliminaire(法语)

1789 年;1790 年英译4,777 词21 分钟Claude 译

馆员评分8.9Claude · AI

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奠定近代化学之书的序言,主张改革名称就是改革思想;行文紧密,但“由已知到未知”至今仍是教学准绳。

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When I began the following Work, my only object was to extend and explain more fully the Memoir which I read at the public meeting of the Academy of Sciences in the month of April 1787, on the necessity of reforming and completing the Nomenclature of Chemistry. While engaged in this employment, I perceived, better than I had ever done before, the justice of the following maxims of the Abbé de Condillac, in his System of Logic, and some other of his works.

我开始写下面这部著作的时候,唯一的目的,是扩充并更充分地阐明我在 1787 年 4 月科学院公开会议上宣读的那篇论文,那篇论文讲的是改革和完善化学命名法的必要性。在从事这项工作的时候,我比以往任何时候都更清楚地看到,孔狄亚克神父在他的《逻辑学》和其他一些著作里提出的下面这些格言是多么正确。

"We think only through the medium of words.—Languages are true analytical methods.—Algebra, which is adapted to its purpose in every species of expression, in the most simple, most exact, and best manner possible, is at the same time a language and an analytical method.—The art of reasoning is nothing more than a language well arranged."

“我们只有通过词语的媒介才能思维。——语言是真正的分析方法。——代数在每一种表达中都适合它的目的,以最简单、最准确、最好的方式表达,它既是一种语言,同时又是一种分析方法。——推理的艺术,不过是一种安排得很好的语言。”

Thus, while I thought myself employed only in forming a Nomenclature, and while I proposed to myself nothing more than to improve the chemical language, my work transformed itself by degrees, without my being able to prevent it, into a treatise upon the Elements of Chemistry.

就这样,当我以为自己只是在制定一套命名法,给自己定下的目标只不过是改进化学的语言时,我的著作却不知不觉地、我无法阻止地,一步一步变成了一部关于化学基础的论著。

The impossibility of separating the nomenclature of a science from the science itself, is owing to this, that every branch of physical science must consist of three things; the series of facts which are the objects of the science, the ideas which represent these facts, and the words by which these ideas are expressed. Like three impressions of the same seal, the word ought to produce the idea, and the idea to be a picture of the fact. And, as ideas are preserved and communicated by means of words, it necessarily follows that we cannot improve the language of any science without at the same time improving the science itself; neither can we, on the other hand, improve a science, without improving the language or nomenclature which belongs to it. However certain the facts of any science may be, and, however just the ideas we may have formed of these facts, we can only communicate false impressions to others, while we want words by which these may be properly expressed.

一门科学的命名法之所以不可能同这门科学本身分开,是因为每一门自然科学都必然由三样东西构成:作为这门科学对象的一系列事实,代表这些事实的观念,以及表达这些观念的词语。词语应当产生观念,观念应当是事实的图画,就像同一枚印章盖出的三个印记。既然观念是靠词语来保存和传达的,那么必然的结论就是:我们不能改进任何一门科学的语言,而不同时改进这门科学本身;另一方面,我们也不能改进一门科学,而不改进属于它的语言或命名法。无论一门科学的事实多么确实,无论我们对这些事实形成的观念多么正确,只要我们缺少能够恰当地表达它们的词语,我们就只能把错误的印象传达给别人。

To those who will consider it with attention, the first part of this treatise will afford frequent proofs of the truth of the above observations. But as, in the conduct of my work, I have been obliged to observe an order of arrangement essentially differing from what has been adopted in any other chemical work yet published, it is proper that I should explain the motives which have led me to do so.

对于那些愿意用心考虑的人,这部论著的第一部分将会经常提供上述看法正确的证据。但是,由于在写作这部著作时,我不得不遵循一种同迄今出版的任何化学著作所采用的都根本不同的编排次序,我应当说明一下促使我这样做的动机。

It is a maxim universally admitted in geometry, and indeed in every branch of knowledge, that, in the progress of investigation, we should proceed from known facts to what is unknown. In early infancy, our ideas spring from our wants; the sensation of want excites the idea of the object by which it is to be gratified. In this manner, from a series of sensations, observations, and analyses, a successive train of ideas arises, so linked together, that an attentive observer may trace back to a certain point the order and connection of the whole sum of human knowledge.

在几何学中,而且实际上在每一门知识中,都公认这样一条准则:在探究的进程中,我们应当从已知的事实走向未知的东西。在婴儿时期,我们的观念产生于我们的需要;需要的感觉,唤起能满足这种需要的对象的观念。就这样,从一系列的感觉、观察和分析中,产生出一连串前后相继的观念,它们彼此紧密相连,一个细心的观察者可以把人类全部知识的次序和联系追溯到某一点。

When we begin the study of any science, we are in a situation, respecting that science, similar to that of children; and the course by which we have to advance is precisely the same which Nature follows in the formation of their ideas. In a child, the idea is merely an effect produced by a sensation; and, in the same manner, in commencing the study of a physical science, we ought to form no idea but what is a necessary consequence, and immediate effect, of an experiment or observation. Besides, he that enters upon the career of science, is in a less advantageous situation than a child who is acquiring his first ideas. To the child, Nature gives various means of rectifying any mistakes he may commit respecting the salutary or hurtful qualities of the objects which surround him. On every occasion his judgments are corrected by experience; want and pain are the necessary consequences arising from false judgment; gratification and pleasure are produced by judging aright. Under such masters, we cannot fail to become well informed; and we soon learn to reason justly, when want and pain are the necessary consequences of a contrary conduct.

当我们开始研究任何一门科学的时候,我们在这门科学面前的处境,同儿童的处境相似;我们必须遵循的前进道路,正是自然在儿童形成观念时所遵循的道路。在儿童身上,观念只是感觉所产生的一个结果;同样,在开始研究一门自然科学时,我们也不应当形成任何观念,除非它是一次实验或观察的必然结果和直接效果。此外,走上科学道路的人,处境还不如一个正在获得最初观念的儿童有利。自然给了儿童种种手段,来纠正他对周围事物的有益或有害的性质可能犯的任何错误。在每一个场合,他的判断都受到经验的纠正;匮乏和痛苦是错误判断的必然后果,满足和快乐则来自正确的判断。在这样的老师手下,我们不会不变得见多识广;当匮乏和痛苦是相反行为的必然后果时,我们很快就学会了正确地推理。

In the study and practice of the sciences it is quite different; the false judgments we form neither affect our existence nor our welfare; and we are not forced by any physical necessity to correct them. Imagination, on the contrary, which is ever wandering beyond the bounds of truth, joined to self-love and that self-confidence we are so apt to indulge, prompt us to draw conclusions which are not immediately derived from facts; so that we become in some measure interested in deceiving ourselves. Hence it is by no means to be wondered, that, in the science of physics in general, men have often made suppositions, instead of forming conclusions. These suppositions, handed down from one age to another, acquire additional weight from the authorities by which they are supported, till at last they are received, even by men of genius, as fundamental truths.

在科学的研究和实践中,情况就完全不同了;我们形成的错误判断,既不影响我们的生存,也不影响我们的福祉;也没有任何物理的必然性迫使我们去纠正它们。相反,总是游荡在真理边界之外的想象力,加上我们那么容易放纵的自爱和自信,促使我们得出一些并非直接从事实推出的结论;结果我们在某种程度上变得乐于欺骗自己。因此,在一般的物理科学中,人们常常作出假设,而不是得出结论,这就一点也不奇怪了。这些假设一代一代传下去,又因为支持它们的权威而增加了分量,直到最后,连有天才的人也把它们当作基本真理接受下来。

The only method of preventing such errors from taking place, and of correcting them when formed, is to restrain and simplify our reasoning as much as possible. This depends entirely upon ourselves, and the neglect of it is the only source of our mistakes. We must trust to nothing but facts: These are presented to us by Nature, and cannot deceive. We ought, in every instance, to submit our reasoning to the test of experiment, and never to search for truth but by the natural road of experiment and observation. Thus mathematicians obtain the solution of a problem by the mere arrangement of data, and by reducing their reasoning to such simple steps, to conclusions so very obvious, as never to lose sight of the evidence which guides them.

防止这类错误发生、并在它们形成后加以纠正的唯一方法,就是尽可能地约束和简化我们的推理。这完全取决于我们自己,忽视这一点,是我们犯错误的唯一根源。我们只能信赖事实:事实是自然呈现给我们的,不会欺骗人。在每一个场合,我们都应当让我们的推理接受实验的检验,除了实验和观察这条自然的道路以外,决不用别的方法去寻求真理。数学家们就是这样,仅仅通过安排已知条件,把推理化为非常简单的步骤,化为非常明显的结论,从而永远不会看不见引导他们的证据,求得问题的解答。

Thoroughly convinced of these truths, I have imposed upon myself, as a law, never to advance but from what is known to what is unknown; never to form any conclusion which is not an immediate consequence necessarily flowing from observation and experiment; and always to arrange the facts, and the conclusions which are drawn from them, in such an order as shall render it most easy for beginners in the study of chemistry thoroughly to understand them. Hence I have been obliged to depart from the usual order of courses of lectures and of treatises upon chemistry, which always assume the first principles of the science, as known, when the pupil or the reader should never be supposed to know them till they have been explained in subsequent lessons. In almost every instance, these begin by treating of the elements of matter, and by explaining the table of affinities, without considering, that, in so doing, they must bring the principal phenomena of chemistry into view at the very outset: They make use of terms which have not been defined, and suppose the science to be understood by the very persons they are only beginning to teach. It ought likewise to be considered, that very little of chemistry can be learned in a first course, which is hardly sufficient to make the language of the science familiar to the ears, or the apparatus familiar to the eyes. It is almost impossible to become a chemist in less than three or four years of constant application.

我完全确信这些真理,所以给自己定下一条法则:永远只从已知走向未知;决不作出任何不是从观察和实验必然直接得出的结论;总是把事实和从事实得出的结论,按照最便于初学化学的人透彻理解的次序来排列。因此,我不得不离开化学讲课和化学论著的通常次序,那种次序总是把这门科学的基本原理当作已知的,而在后面的课程把它们解释清楚之前,本不应当假定学生或读者已经知道它们。在几乎每一种情况下,这些课程和论著都是从论述物质的元素、解释亲和力表开始的,却没有考虑到,这样做的时候,它们就必须一开头就把化学的主要现象摆出来:它们使用了没有下过定义的术语,假定这门科学已经为他们刚刚开始教的那些人所理解了。还应当考虑到,在第一门课程里能学到的化学是很少的,第一门课程几乎不足以让耳朵熟悉这门科学的语言,让眼睛熟悉它的仪器。一个人不经过三四年持续不断的努力,几乎不可能成为一个化学家。

These inconveniencies are occasioned not so much by the nature of the subject, as by the method of teaching it; and, to avoid them, I was chiefly induced to adopt a new arrangement of chemistry, which appeared to me more consonant to the order of Nature. I acknowledge, however, that in thus endeavouring to avoid difficulties of one kind, I have found myself involved in others of a different species, some of which I have not been able to remove; but I am persuaded, that such as remain do not arise from the nature of the order I have adopted, but are rather consequences of the imperfection under which chemistry still labours. This science still has many chasms, which interrupt the series of facts, and often render it extremely difficult to reconcile them with each other: It has not, like the elements of geometry, the advantage of being a complete science, the parts of which are all closely connected together: Its actual progress, however, is so rapid, and the facts, under the modern doctrine, have assumed so happy an arrangement, that we have ground to hope, even in our own times, to see it approach near to the highest state of perfection of which it is susceptible.

这些不便,与其说是由题材的性质造成的,不如说是由教授它的方法造成的;正是为了避免它们,我才主要被引导去采用一种新的化学编排,它在我看来更符合自然的次序。不过我承认,在这样努力避免一种困难的时候,我发现自己陷入了另一类困难,其中有一些我还没能消除;但是我深信,那些剩下的困难,并不是由我所采用的次序的性质引起的,而毋宁说是化学至今仍然存在的不完善的结果。这门科学仍然有许多空白,打断了事实的系列,常常使它们极难互相协调:它不像几何原理那样,具有一门完整的科学的优点,各部分都紧密相连:然而它实际的进展是如此迅速,在新学说之下,事实已经有了如此美好的编排,所以我们有理由希望,甚至就在我们自己的时代,就能看到它接近于它所能达到的最高完善状态。

The rigorous law from which I have never deviated, of forming no conclusions which are not fully warranted by experiment, and of never supplying the absence of facts, has prevented me from comprehending in this work the branch of chemistry which treats of affinities, although it is perhaps the best calculated of any part of chemistry for being reduced into a completely systematic body. Messrs Geoffroy, Gellert, Bergman, Scheele, De Morveau, Kirwan, and many others, have collected a number of particular facts upon this subject, which only wait for a proper arrangement; but the principal data are still wanting, or, at least, those we have are either not sufficiently defined, or not sufficiently proved, to become the foundation upon which to build so very important a branch of chemistry. This science of affinities, or elective attractions, holds the same place with regard to the other branches of chemistry, as the higher or transcendental geometry does with respect to the simpler and elementary part; and I thought it improper to involve those simple and plain elements, which I flatter myself the greatest part of my readers will easily understand, in the obscurities and difficulties which still attend that other very useful and necessary branch of chemical science.

我从来没有背离过一条严格的法则:不作任何没有得到实验充分保证的结论,决不填补事实的空缺。这条法则使我没有把化学中论述亲和力的那个分支收进这部著作,虽然在化学的所有部分中,它也许最适合被归结为一个完全系统的整体。若弗鲁瓦、格勒特、贝格曼、舍勒、德莫尔沃、柯万诸位先生以及许多别的人,已经收集了许多这方面的具体事实,只等着加以适当的编排;但是主要的资料仍然缺乏,或者至少,我们已有的资料要么定义得不够,要么证明得不够,还不能成为建立这样一个非常重要的化学分支的基础。这门关于亲和力或选择性吸引的科学,同化学其他分支的关系,就像高等几何或超越几何同较简单的初等部分的关系一样;我认为,把那些简单明白、我自信大多数读者都能容易理解的基础,卷进那个非常有用、非常必要的化学分支至今仍然存在的晦涩和困难之中,是不适当的。

Perhaps a sentiment of self-love may, without my perceiving it, have given additional force to these reflections. Mr de Morveau is at present engaged in publishing the article Affinity in the Methodical Encyclopaedia; and I had more reasons than one to decline entering upon a work in which he is employed.

也许,一种自爱的情感在我没有察觉的时候,给这些考虑增添了力量。德莫尔沃先生目前正在《方法百科全书》中发表“亲和力”这个条目;我有不止一个理由不去涉足他正在从事的一项工作。

It will, no doubt, be a matter of surprise, that in a treatise upon the elements of chemistry, there should be no chapter on the constituent and elementary parts of matter; but I shall take occasion, in this place, to remark, that the fondness for reducing all the bodies in nature to three or four elements, proceeds from a prejudice which has descended to us from the Greek Philosophers. The notion of four elements, which, by the variety of their proportions, compose all the known substances in nature, is a mere hypothesis, assumed long before the first principles of experimental philosophy or of chemistry had any existence. In those days, without possessing facts, they framed systems; while we, who have collected facts, seem determined to reject them, when they do not agree with our prejudices. The authority of these fathers of human philosophy still carry great weight, and there is reason to fear that it will even bear hard upon generations yet to come.

在一部论述化学基础的书里,竟然没有一章论述物质的组成部分和基本部分,这无疑会使人感到惊讶;但是我要借这个机会在这里指出:喜欢把自然界一切物体都归结为三种或四种元素,是出于一种从希腊哲学家那里传给我们的偏见。认为四种元素以不同的比例组成了自然界一切已知物质的观念,只是一种假说,远在实验哲学或化学的最初原理存在之前就被假定了。在那些日子里,他们没有掌握事实,就构造体系;而我们这些已经收集了事实的人,在事实同我们的偏见不一致的时候,却似乎决心拒绝它们。这些人类哲学之父的权威,至今仍有很大的分量,而且有理由担心,它甚至还会沉重地压在未来的世代身上。

It is very remarkable, that, notwithstanding of the number of philosophical chemists who have supported the doctrine of the four elements, there is not one who has not been led by the evidence of facts to admit a greater number of elements into their theory. The first chemists that wrote after the revival of letters, considered sulphur and salt as elementary substances entering into the composition of a great number of substances; hence, instead of four, they admitted the existence of six elements. Beccher assumes the existence of three kinds of earth, from the combination of which, in different proportions, he supposed all the varieties of metallic substances to be produced. Stahl gave a new modification to this system; and succeeding chemists have taken the liberty to make or to imagine changes and additions of a similar nature. All these chemists were carried along by the influence of the genius of the age in which they lived, which contented itself with assertions without proofs; or, at least, often admitted as proofs the slightest degrees of probability, unsupported by that strictly rigorous analysis required by modern philosophy.

很值得注意的是,尽管支持四元素学说的哲学化学家为数众多,却没有一个人不是被事实的证据引导着,在他们的理论中承认了更多的元素。文艺复兴以后写作的第一批化学家,认为硫和盐是进入大量物质组成的元素物质;因此他们承认存在六种元素,而不是四种。贝歇尔假定存在三种土,他设想,各种金属物质都是由这三种土以不同的比例化合而产生的。施塔尔对这个体系作了新的修改;后来的化学家们也随意作了或者想象出了类似的改变和补充。所有这些化学家,都是被他们所生活的时代的风气带着走的,那种风气满足于没有证明的断言;或者至少,常常把最微小程度的可能性当作证明,而没有现代哲学所要求的那种极其严格的分析作为支持。

All that can be said upon the number and nature of elements is, in my opinion, confined to discussions entirely of a metaphysical nature. The subject only furnishes us with indefinite problems, which may be solved in a thousand different ways, not one of which, in all probability, is consistent with nature. I shall therefore only add upon this subject, that if, by the term elements, we mean to express those simple and indivisible atoms of which matter is composed, it is extremely probable we know nothing at all about them; but, if we apply the term elements, or principles of bodies, to express our idea of the last point which analysis is capable of reaching, we must admit, as elements, all the substances into which we are capable, by any means, to reduce bodies by decomposition. Not that we are entitled to affirm, that these substances we consider as simple may not be compounded of two, or even of a greater number of principles; but, since these principles cannot be separated, or rather since we have not hitherto discovered the means of separating them, they act with regard to us as simple substances, and we ought never to suppose them compounded until experiment and observation has proved them to be so.

在我看来,关于元素的数目和性质所能说的一切,都局限于完全是形而上学性质的讨论。这个题目只给我们提供一些不确定的问题,可以用一千种不同的方法去解答,而其中很可能没有一种是符合自然的。因此,关于这个题目,我只补充一点:如果我们用“元素”这个词来表示组成物质的那些简单而不可分的原子,那么极有可能,我们对它们一无所知;但是,如果我们用“元素”或“物体的要素”这个词,来表达我们关于分析所能达到的最后一点的观念,那么,凡是我们能用任何方法通过分解把物体还原成的物质,我们都必须承认它们是元素。这并不是说,我们有权断言,这些我们认为是简单的物质,就不可能是由两种甚至更多的要素化合而成的;而是说,既然这些要素不能被分离,或者毋宁说,既然我们迄今还没有发现分离它们的方法,那么对我们来说,它们的作用就和简单物质一样,在实验和观察证明它们是化合物之前,我们决不应当假定它们是化合物。

The foregoing reflections upon the progress of chemical ideas naturally apply to the words by which these ideas are to be expressed. Guided by the work which, in the year 1787, Messrs de Morveau, Berthollet, de Fourcroy, and I composed upon the Nomenclature of Chemistry, I have endeavoured, as much as possible, to denominate simple bodies by simple terms, and I was naturally led to name these first. It will be recollected, that we were obliged to retain that name of any substance by which it had been long known in the world, and that in two cases only we took the liberty of making alterations; first, in the case of those which were but newly discovered, and had not yet obtained names, or at least which had been known but for a short time, and the names of which had not yet received the sanction of the public; and, secondly, when the names which had been adopted, whether by the ancients or the moderns, appeared to us to express evidently false ideas, when they confounded the substances, to which they were applied, with others possessed of different, or perhaps opposite qualities. We made no scruple, in this case, of substituting other names in their room, and the greatest number of these were borrowed from the Greek language. We endeavoured to frame them in such a manner as to express the most general and the most characteristic quality of the substances; and this was attended with the additional advantage both of assisting the memory of beginners, who find it difficult to remember a new word which has no meaning, and of accustoming them early to admit no word without connecting with it some determinate idea.

上面关于化学观念进展的这些思考,自然也适用于表达这些观念的词语。在 1787 年德莫尔沃、贝托莱、德富尔克鲁瓦诸位先生和我共同撰写的关于化学命名法的那部著作的指导下,我尽可能地用简单的名称来称呼简单的物体,而且我自然而然地首先给它们命名。大家会记得,我们不得不保留任何一种物质久已为世人所知的名称,只有在两种情况下,我们才擅自作了改动:第一,是那些新近才发现、还没有得到名称的物质,或者至少是才知道不久、名称还没有得到公众认可的物质;第二,是当古人或今人所采用的名称,在我们看来显然表达了错误的观念,把它们所指的物质,同另一些具有不同的、甚至相反的性质的物质混淆起来的时候。在这种情况下,我们毫不犹豫地用别的名称来代替它们,其中大多数是从希腊语借来的。我们努力使这些名称能够表达物质最一般、最有特征的性质;这样做还有一个额外的好处:既有助于初学者的记忆,他们觉得一个没有意义的新词很难记住,又使他们早早习惯于不接受任何一个不同某种确定的观念相联系的词。

To those bodies which are formed by the union of several simple substances we gave new names, compounded in such a manner as the nature of the substances directed; but, as the number of double combinations is already very considerable, the only method by which we could avoid confusion, was to divide them into classes. In the natural order of ideas, the name of the class or genus is that which expresses a quality common to a great number of individuals: The name of the species, on the contrary, expresses a quality peculiar to certain individuals only.

对于那些由几种简单物质结合而成的物体,我们按照物质的性质所指示的方式,给了它们组合而成的新名称;但是,由于二元化合物的数目已经相当大,我们能够避免混乱的唯一方法,就是把它们分成类。按照观念的自然次序,类或属的名称,表达的是许多个体共有的一种性质;相反,种的名称,表达的是只有某些个体才有的一种性质。

These distinctions are not, as some may imagine, merely metaphysical, but are established by Nature. "A child," says the Abbé de Condillac, "is taught to give the name tree to the first one which is pointed out to him. The next one he sees presents the same idea, and he gives it the same name. This he does likewise to a third and a fourth, till at last the word tree, which he first applied to an individual, comes to be employed by him as the name of a class or a genus, an abstract idea, which comprehends all trees in general. But, when he learns that all trees serve not the same purpose, that they do not all produce the same kind of fruit, he will soon learn to distinguish them by specific and particular names." This is the logic of all the sciences, and is naturally applied to chemistry.

这些区分并不像有些人可能想象的那样,只是形而上学的,而是由自然确立的。孔狄亚克神父说:“教给孩子的,是把第一棵指给他看的树叫作‘树’。他看到的第二棵树呈现出同样的观念,他就给它同样的名称。对第三棵、第四棵,他也这样做,直到最后,他起初用于一个个体的‘树’这个词,被他用作一个类或一个属的名称,一个包括一切树木的抽象观念。但是,当他知道并不是所有的树都有同样的用途,并不是所有的树都结同样的果实时,他很快就会学会用种的、特殊的名称来区分它们。”这是一切科学的逻辑,自然也适用于化学。

The acids, for example, are compounded of two substances, of the order of those which we consider as simple; the one constitutes acidity, and is common to all acids, and, from this substance, the name of the class or the genus ought to be taken; the other is peculiar to each acid, and distinguishes it from the rest, and from this substance is to be taken the name of the species. But, in the greatest number of acids, the two constituent elements, the acidifying principle, and that which it acidifies, may exist in different proportions, constituting all the possible points of equilibrium or of saturation. This is the case in the sulphuric and the sulphurous acids; and these two states of the same acid we have marked by varying the termination of the specific name.

例如,酸是由两种物质组成的,这两种物质属于我们认为是简单的那一类;一种构成酸性,是一切酸所共有的,类或属的名称应当取自这种物质;另一种是每一种酸所特有的,使它同其余的酸区别开来,种的名称就应当取自这种物质。但是,在大多数酸里,两种组成元素,即致酸的要素和被它酸化的要素,可以以不同的比例存在,构成一切可能的平衡点或饱和点。硫酸和亚硫酸的情形就是这样;同一种酸的这两种状态,我们用改变种名的词尾来标明。

Metallic substances which have been exposed to the joint action of the air and of fire, lose their metallic lustre, increase in weight, and assume an earthy appearance. In this state, like the acids, they are compounded of a principle which is common to all, and one which is peculiar to each. In the same way, therefore, we have thought proper to class them under a generic name, derived from the common principle; for which purpose, we adopted the term oxyd; and we distinguish them from each other by the particular name of the metal to which each belongs.

金属物质受到空气和火的共同作用之后,会失去它们的金属光泽,增加重量,呈现出土的样子。在这种状态下,它们像酸一样,是由一种一切金属所共有的要素和一种每一种金属所特有的要素组成的。因此,我们认为应当用同样的方式,用一个取自共同要素的属名把它们归为一类;为此,我们采用了“氧化物”(oxyd)这个名称;我们再用每一种所属的金属的特殊名称来把它们彼此区分开来。

Combustible substances, which in acids and metallic oxyds are a specific and particular principle, are capable of becoming, in their turn, common principles of a great number of substances. The sulphurous combinations have been long the only known ones in this kind. Now, however, we know, from the experiments of Messrs Vandermonde, Monge, and Berthollet, that charcoal may be combined with iron, and perhaps with several other metals; and that, from this combination, according to the proportions, may be produced steel, plumbago, &c. We know likewise, from the experiments of M. Pelletier, that phosphorus may be combined with a great number of metallic substances. These different combinations we have classed under generic names taken from the common substance, with a termination which marks this analogy, specifying them by another name taken from that substance which is proper to each.

可燃物质,在酸和金属氧化物中是种的、特殊的要素,反过来也能成为许多物质的共同要素。长期以来,硫的化合物是这一类中唯一已知的。不过,现在我们从范德蒙德、蒙日和贝托莱诸位先生的实验知道,木炭可以同铁化合,也许还能同其他几种金属化合;根据比例的不同,从这种化合中可以产生钢、石墨等等。我们从佩尔蒂埃先生的实验中还知道,磷可以同许多种金属物质化合。这些不同的化合物,我们用取自共同物质的属名来分类,加上一个标明这种类似关系的词尾,再用取自每一种所特有的那种物质的另一个名称来具体说明它们。

The nomenclature of bodies compounded of three simple substances was attended with still greater difficulty, not only on account of their number, but, particularly, because we cannot express the nature of their constituent principles without employing more compound names. In the bodies which form this class, such as the neutral salts, for instance, we had to consider, 1st, The acidifying principle, which is common to them all; 2d, The acidifiable principle which constitutes their peculiar acid; 3d, The saline, earthy, or metallic basis, which determines the particular species of salt. Here we derived the name of each class of salts from the name of the acidifiable principle common to all the individuals of that class; and distinguished each species by the name of the saline, earthy, or metallic basis, which is peculiar to it.

由三种简单物质组成的物体的命名,困难更大,不仅因为它们数目多,尤其是因为不使用更复杂的名称,我们就无法表达它们的组成要素的性质。在构成这一类的物体中,例如中性盐,我们必须考虑:第一,致酸的要素,它是一切中性盐所共有的;第二,可酸化的要素,它构成它们特有的酸;第三,盐性的、土性的或金属的基,它决定盐的具体的种。在这里,我们从这一类所有个体共有的可酸化要素的名称,得出每一类盐的名称;再用每一种所特有的盐性的、土性的或金属的基的名称来区分每一个种。

A salt, though compounded of the same three principles, may, nevertheless, by the mere difference of their proportion, be in three different states. The nomenclature we have adopted would have been defective, had it not expressed these different states; and this we attained chiefly by changes of termination uniformly applied to the same state of the different salts.

一种盐,虽然由同样的三种要素组成,却可以仅仅由于它们比例的不同而处于三种不同的状态。我们所采用的命名法,如果不能表达这些不同的状态,就是有缺陷的;我们主要是通过对不同的盐的同一状态一律改变词尾来做到这一点的。

In short, we have advanced so far, that from the name alone may be instantly found what the combustible substance is which enters into any combination; whether that combustible substance be combined with the acidifying principle, and in what proportion; what is the state of the acid; with what basis it is united; whether the saturation be exact, or whether the acid or the basis be in excess.

总之,我们已经做到了这样的地步:仅仅从名称,就能立刻看出进入任何一种化合物的可燃物质是什么;这种可燃物质是否同致酸的要素化合,比例如何;酸处于什么状态;它同什么基结合;饱和是否恰好,还是酸或基过量。

It may be easily supposed that it was not possible to attain all these different objects without departing, in some instances, from established custom, and adopting terms which at first sight will appear uncouth and barbarous. But we considered that the ear is soon habituated to new words, especially when they are connected with a general and rational system. The names, besides, which were formerly employed, such as powder of algaroth, salt of alembroth, pompholix, phagadenic water, turbith mineral, colcothar, and many others, were neither less barbarous nor less uncommon. It required a great deal of practice, and no small degree of memory, to recollect the substances to which they were applied, much more to recollect the genus of combination to which they belonged. The names of oil of tartar per deliquium, oil of vitriol, butter of arsenic and of antimony, flowers of zinc, &c. were still more improper, because they suggested false ideas: For, in the whole mineral kingdom, and particularly in the metallic class, there exists no such thing as butters, oils, or flowers; and, in short, the substances to which they give these fallacious names, are nothing less than rank poisons.

不难想见,要达到所有这些不同的目的,就不可能不在某些情况下背离既定的习惯,采用一些乍看起来显得生硬粗野的名称。但是我们考虑到,耳朵很快就会习惯新词,尤其是当这些新词同一个普遍而合理的体系联系在一起的时候。此外,从前使用的那些名称,例如“阿尔加罗特粉”“阿伦布罗特盐”“庞福利克斯”“腐蚀水”“矿物透必特”“铁丹”,以及许多别的名称,也并不比新名称更不生硬,更不罕见。要记住它们所指的物质,需要大量的练习和不小的记忆力,更不用说记住它们属于哪一类化合物了。“潮解的酒石油”“矾油”“砷脂”和“锑脂”、“锌华”等等名称,就更不恰当了,因为它们暗示了错误的观念:因为在整个矿物界,特别是在金属类里,根本没有什么油、脂或花这样的东西;总之,被它们冠以这些虚假名称的物质,其实都是剧毒。

When we published our essay on the nomenclature of chemistry, we were reproached for having changed the language which was spoken by our masters, which they distinguished by their authority, and handed down to us. But those who reproach us on this account, have forgotten that it was Bergman and Macquer themselves who urged us to make this reformation. In a letter which the learned Professor of Upsal, M. Bergman, wrote, a short time before he died, to M. de Morveau, he bids him spare no improper names; those who are learned, will always be learned, and those who are ignorant will thus learn sooner.

我们发表关于化学命名法的论文时,有人责备我们改变了我们的老师们所说的语言,那种语言是他们以自己的权威确立、传给我们的。但是那些在这一点上责备我们的人忘记了,正是贝格曼和马凯本人督促我们进行这项改革的。乌普萨拉的博学教授贝格曼先生,在他去世前不久写给德莫尔沃先生的一封信里,嘱咐他不要放过任何一个不恰当的名称;有学问的人永远会有学问,而无知的人这样会学得更快。

There is an objection to the work which I am going to present to the public, which is perhaps better founded, that I have given no account of the opinion of those who have gone before me; that I have stated only my own opinion, without examining that of others. By this I have been prevented from doing that justice to my associates, and more especially to foreign chemists, which I wished to render them. But I beseech the reader to consider, that, if I had filled an elementary work with a multitude of quotations; if I had allowed myself to enter into long dissertations on the history of the science, and the works of those who have studied it, I must have lost sight of the true object I had in view, and produced a work, the reading of which must have been extremely tiresome to beginners. It is not to the history of the science, or of the human mind, that we are to attend in an elementary treatise: Our only aim ought to be ease and perspicuity, and with the utmost care to keep every thing out of view which might draw aside the attention of the student; it is a road which we should be continually rendering more smooth, and from which we should endeavour to remove every obstacle which can occasion delay. The sciences, from their own nature, present a sufficient number of difficulties, though we add not those which are foreign to them. But, besides this, chemists will easily perceive, that, in the first part of my work, I make very little use of any experiments but those which were made by myself: If at any time I have adopted, without acknowledgment, the experiments or the opinions of M. Berthollet, M. Fourcroy, M. de la Place, M. Monge, or, in general, of any of those whose principles are the same with my own, it is owing to this circumstance, that frequent intercourse, and the habit of communicating our ideas, our observations, and our way of thinking to each other, has established between us a sort of community of opinions, in which it is often difficult for every one to know his own.

对于我将要奉献给公众的这部著作,有一种反对意见也许更有根据:我没有介绍我的前人的见解;我只陈述了我自己的见解,而没有考察别人的见解。这使我没能给我的同伴们,尤其是外国的化学家们,以我本想给予的公正。但是我恳请读者考虑:如果我在一部基础著作里塞满大量的引文;如果我让自己大段大段地论述这门科学的历史,以及研究过它的那些人的著作,我就一定会看不见我心目中的真正目标,写出一部初学者读起来必定极其乏味的书。在一部基础论著中,我们要关注的不是科学的历史,也不是人类心灵的历史:我们唯一的目标应当是平易和明晰,并且极其小心地把一切可能分散学生注意力的东西都排除在视线之外;这是一条我们应当不断把它修得更平坦的道路,我们应当努力从路上清除一切可能引起耽搁的障碍。各门科学由于它们本身的性质,已经有足够多的困难,用不着我们再添上一些与它们无关的困难。此外,化学家们很容易看出,在我这部著作的第一部分里,除了我自己做的实验以外,我很少使用别的实验:如果我有时没有说明就采用了贝托莱先生、富尔克鲁瓦先生、拉普拉斯先生、蒙日先生,或者一般说来,任何一位与我原理相同的人的实验或见解,那是由于这样一种情形:经常的交往,以及彼此交流我们的观念、观察和思考方式的习惯,已经在我们之间建立起一种意见的共有,在这种共有之中,往往每一个人都很难分清哪些是他自己的。

The remarks I have made on the order which I thought myself obliged to follow in the arrangement of proofs and ideas, are to be applied only to the first part of this work. It is the only one which contains the general sum of the doctrine I have adopted, and to which I wished to give a form completely elementary.

我关于证据和观念的编排所认为必须遵循的次序所作的说明,只适用于这部著作的第一部分。只有这一部分包含了我所采用的学说的总体,我希望给它一种完全基础性的形式。

The second part is composed chiefly of tables of the nomenclature of the neutral salts. To these I have only added general explanations, the object of which was to point out the most simple processes for obtaining the different kinds of known acids. This part contains nothing which I can call my own, and presents only a very short abridgment of the results of these processes, extracted from the works of different authors.

第二部分主要由中性盐的命名表组成。对这些表,我只加上了一些总的说明,目的是指出获得各种已知的酸的最简单的方法。这一部分没有什么可以称为我自己的东西,只是对这些方法的结果作了一个很简短的摘要,摘自不同作者的著作。

In the third part, I have given a description, in detail, of all the operations connected with modern chemistry. I have long thought that a work of this kind was much wanted, and I am convinced it will not be without use. The method of performing experiments, and particularly those of modern chemistry, is not so generally known as it ought to be; and had I, in the different memoirs which I have presented to the Academy, been more particular in the detail of the manipulations of my experiments, it is probable I should have made myself better understood, and the science might have made a more rapid progress. The order of the different matters contained in this third part appeared to me to be almost arbitrary; and the only one I have observed was to class together, in each of the chapters of which it is composed, those operations which are most connected with one another. I need hardly mention that this part could not be borrowed from any other work, and that, in the principal articles it contains, I could not derive assistance from any thing but the experiments which I have made myself.

在第三部分里,我详细描述了与现代化学有关的一切操作。我早就认为非常需要一部这样的著作,我也相信它不会没有用处。做实验的方法,特别是现代化学的实验方法,并不像它应当的那样广为人知;如果我在向科学院提交的各篇论文中,把我的实验操作的细节写得更详细一些,我大概会让别人更好地理解我,这门科学也许会进步得更快。这第三部分所包含的各种内容的次序,在我看来几乎是任意的;我所遵循的唯一次序,是在组成这一部分的每一章里,把那些彼此最有联系的操作归在一起。我几乎不必说,这一部分不可能从任何别的著作中借来,在它所包含的主要条目中,除了我自己做的实验以外,我不能从任何东西那里得到帮助。

I shall conclude this preface by transcribing, literally, some observations of the Abbé de Condillac, which I think describe, with a good deal of truth, the state of chemistry at a period not far distant from our own. These observations were made on a different subject; but they will not, on this account, have less force, if the application of them be thought just.

我要逐字抄录孔狄亚克神父的几段话来结束这篇序言,我认为这些话相当真实地描述了离我们不远的一个时期化学的状况。这些话本来是针对另一个题目说的;但是如果把它们这样应用被认为是恰当的,它们的力量也不会因此而减少。

'Instead of applying observation to the things we wished to know, we have chosen rather to imagine them. Advancing from one ill founded supposition to another, we have at last bewildered ourselves amidst a multitude of errors. These errors becoming prejudices, are, of course, adopted as principles, and we thus bewilder ourselves more and more. The method, too, by which we conduct our reasonings is as absurd; we abuse words which we do not understand, and call this the art of reasoning. When matters have been brought this length, when errors have been thus accumulated, there is but one remedy by which order can be restored to the faculty of thinking; this is, to forget all that we have learned, to trace back our ideas to their source, to follow the train in which they rise, and, as my Lord Bacon says, to frame the human understanding anew.

“我们没有把观察应用于我们想要知道的事物,而宁愿去想象它们。从一个没有根据的假设走向另一个,我们最后在一大堆错误中迷失了自己。这些错误变成了偏见,自然被当作原理接受下来,于是我们越来越迷失。我们进行推理所用的方法也同样荒唐;我们滥用自己并不理解的词语,还把这叫作推理的艺术。当事情到了这一步,当错误这样积累起来时,就只有一个办法能使思维能力恢复秩序;那就是,忘掉我们学过的一切,把我们的观念追溯到它们的源头,顺着它们产生的次序走下去,并且像培根勋爵所说的那样,重新塑造人类的理解力。

'This remedy becomes the more difficult in proportion as we think ourselves more learned. Might it not be thought that works which treated of the sciences with the utmost perspicuity, with great precision and order, must be understood by every body? The fact is, those who have never studied any thing will understand them better than those who have studied a great deal, and especially than those who have written a great deal.'

“我们越是以为自己有学问,这个办法就越难实行。难道人们不会认为,那些以最大的明晰、极其准确而有条理地论述科学的著作,一定是每一个人都能理解的吗?事实是,从来没有学过任何东西的人,会比学过很多东西的人理解得更好,尤其是比写过很多东西的人理解得更好。”

At the end of the fifth chapter, the Abbé de Condillac adds: 'But, after all, the sciences have made progress, because philosophers have applied themselves with more attention to observe, and have communicated to their language that precision and accuracy which they have employed in their observations: In correcting their language they reason better.'

在第五章的末尾,孔狄亚克神父又说:“但是,毕竟各门科学已经进步了,因为哲学家们更加专心致志地去观察,并且把他们在观察中所用的那种精确和准确,传给了他们的语言:在纠正他们的语言的时候,他们推理得更好了。”

馆员注 · Claude(AI),二号馆员

拉瓦锡的《化学基础论》是使现代化学走上正轨的那本书。它用一份可以操作的、不能再分解的物质清单,取代了四元素说;用氧而不是燃素来解释燃烧;并给物质起了化学家至今仍在使用的系统名称。这篇序言说明,为什么一场词语的改革变成了一场科学的改革,以及为什么应当引导初学者只从已知走向未知。第二年,爱丁堡的外科医生罗伯特·克尔把它译成了英文。

标签:发现学习思考

版本记

权利

1789 年以法文出版;拉瓦锡卒于 1794 年。译者罗伯特·克尔卒于 1813 年;他的译本 1790 年出版。

已按澳大利亚、欧盟、英国、中国大陆和美国的规则核对(截至 2026 年 10 月 11 日)。

仅供参考,不是法律意见。

来源

Project Gutenberg取于 2026 年 10 月 11 日

译文

Robert Kerr (1757–1813),1790 年

中文:Claude(AI),2026 · CC0 1.0

馆藏号

S-006206coldlibrary.com/s/006206

引用与保存

纯文本(.txt,51 KB)

完整著录
题名
Traité élémentaire de chimie: Discours préliminaireElements of Chemistry: The Author’s Preface化学基础论:作者序
作者
安托万·拉瓦锡 Antoine-Laurent de Lavoisier (1743–1794)
年代
1789 年;1790 年英译
体裁
散文
语种
英语
原文语种
法语
版本
《化学基础论:按新的系统次序编排,包括一切现代发现》的序言,罗伯特·克尔译(爱丁堡:威廉·克里奇,1790),据古登堡计划电子书第 30775 号,并与 1790 年版三个印本的扫描本对校。依原书扫描本改正录入的三处笔误:“colcathar”改为“colcothar”,“the slighted degrees”改为“the slightest degrees of probability”,“Abbe”改为“Abbé”。录入本对原书一处误印的改正(“aranged”改为“arranged”)予以保留;克尔带苏格兰味的“notwithstanding of”和原书的“still carry”照印本保留。
本副本

本馆不附加任何权利。Claude 的注释和译文以 CC0 1.0 发布。

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